Mo-doped tungsten trioxide nanorod may be prepared by hydrothermal method on FTO conductive glass coated with a TiO2 crystal seed layer, which adopts sodium tungstate dihydrate and sodium molybdate dihydrate as main raw materials under different hydrothermal growth conditions (at 180°C, hydrothermal growth time of 5h or 6h). The microstructure, composition and electrochromism performance of the obtained WO3 nanorod at different hydrothermal growth times were studied by means of scanning electron microscope (SEM), energy dispersive spectroscopy (EDS) and X-ray diffraction…
Tungsten Oxide
Industrial grade sodium tungstate is also known as technical pure (TP) sodium tungstate, whose purity is lower than that of guarantee grade (GR), analytical grade (AR), chemical purity (CP) and laboratory purity (LR). These grades are classified in accordance with different uses. The TP sodium tungstate is suitable for the laboratories which are not so strict on the purity requirements. There are many ways to control equipment corrosion in industrial cooling water systems, among which adding corrosion inhibitors is one…
Sodium tungstate dihydrate may be prepared by different methods such as alkaline hydrolysis, crystallization, extraction, soda solution pressure cooking, and so on. Alkaline Hydrolysis to Prepare Sodium Tungstate Dihydrate Step 1: Wolframite ore is crushed to 320 mesh, and alkaline hydrolysis is carried out in reactor with 30% caustic soda. The reaction equation is as follows: MnWO4?FeWO4+4NaOH→2Na2WO4+Fe(OH)2?Mn(OH)2 Step 2: The reaction product obtained in step 1 is reacted with calcium chloride to obtain calcium tungstate. The reaction equation is as…
Analytical reagent sodium tungstate is referred to as sodium tungstate that meets the purity standards, which ensures the scientific precision and reliability of chemical analysis, chemical reaction or physical testing. Coprecipitation Separation of Trace Impurities in Sodium Tungstate and Determination by ICP-AES Using lanthanum hydroxide as co-precipitant, trace metal impurity elements (calcium, cadmium, zinc, iron, manganese, nickel, and zinc) in sodium tungstate were coprecipitated, separated, enriched, and measured by ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometry). Analytical reagent means the sodium…
Sodium tungstate crystal may be prepared by the crystallization of sodium tungstate solution. Removal of Arsenic and Silicon from Sodium Tungstate Solution by Crystallization The removal of arsenic and silicon from impure Na2WO4 solution was investigated by crystallization using the liquors (m(As)/m(WO3)=0.32×10-3~2.94×10-3, m(Si)/m(WO3)=1.26×10-3~5.84×10-3) from middle-grade mixed wolframite and scheelite concentrate decomposed with NaOH by mechanical activation and tungsten residue leached by traditional digestion. The influences of the crystallization ratio and the addition of Al2O3 on removing impurities of As and…
Sodium polytungstate has been found to be used as heavy-liquid to separate and concentrate materials by density with the deepening of research. For example, it can be used to separate the worn carbon composites in brake pads. Sodium polytungstate is a kind of inorganic heavy-liquid with the characteristics of high density and cyclic utilization. And it is nontoxic and easily prepared. Also, the sodium polytungstate density separation operation is simple and stable, and most importantly the physic-chemical property of matter…
Sodium tungstate solution containing high impurities should be purified. Purification of Sodium Tungstate Solution with High Impurities Sodium tungstate solution out of sodium phosphate decomposition of scheelite contains high impurities. To solve this problem, the purifying effects of fluoride (F), phosphorous (P), silicon (Si) and arsenic (As) by basic magnesium carbonate was studied. Effects of basic magnesium carbonate dosage, pH value, reaction temperature, reaction time on impurities purifying were researched. The removal mechanism of impurities was also researched. The results…
Reagent grade sodium tungstate, RG sodium tungstate for short, may be applied for precision analysis and scientific research. Reagent-grade chemical substances are labeled red. There are a variety of chemical reagents, so that it is difficult to prepare them into multiple grades or different specifications at the same time. So, it is hard to obtain reagents of the required purity or grade sometimes. And therefore, it is of significance for users to know how to purify reagents. There are many…
Orthorhombic tungsten trioxide nanoflake may be prepared by hydrothermal method. And the influencing factors on the photocatalytic reaction were studied using photocatalytic degradation of methylene blue by the synthesized WO3 as model. And the photocatalytic properties of orthorhombic WO3 nanoflake were studied by determining the chemical oxygen demand (COD) of methine blue before and after photocatalytic degradation by potassium dichromate method. Hydrothermal Method to Prepare Orthorhombic Tungsten Trioxide Nanoflake The chemical reagents used were of analytical grade and were not…
Monoclinic tungsten trioxide nanoflake may be prepared by chemical precipitation method. Chemical Precipitation Method to Prepare Monoclinic Tungsten Trioxide Nanoflake The chemical reagents used are all analytical reagents (AR) and not purified before use. 1. Weigh 3.0g Na2WO3 and 0.005g CTAB (cetyl trimethyl ammonium bromide), dissolved in 10mL distilled water. Slowly drop 3mL of this solution into 5mL 3mol?L-1 HCL and stir for 1 ~2h. 2. After centrifugal settling of the reacted solution, wash it repeatedly with distilled water and…