Tungsten trioxide nanoflake has potential application prospects in the treatment of organic dye contaminated water. Why does tungsten trioxide nanoflake have potential application prospects in the treatment of organic dye pollution water? The sewage discharge in China is large, and the sewage treatment rate in urban is only 30%, which means that a large amount of untreated sewage is discharged directly to become a secondary source of pollution to the environment, therefore most of the rivers, lakes and urban groundwater…
Tungsten Oxide
Tungsten oxide nanorod may be prepared through a hydrothermal process at 180°C by using sodium sulfate (Na2SO4) as a directing reagent, and may be applied in the photocatalytic degradation of RB under visible light irradiation. Synthesis of Tungsten Trioxide Nanorod 1. Dissolve 2.77g sodium tungstate and 4.77g Na2SO4 in 67.5ml water and stir completely. 2. Adjust the pH to 1.5 with 3mol/L hydrochloric acid (HCL) and stir for 30min. 3. Heat the above solution at 180°C for 48 h. 4.…
Hexagonal tungsten trioxide nanowire may be synthesized by hydrothermal method using Na2WO4?2H2O and HCl as raw materials, K2C2O4 and K2SO4 as structure-directing agents respectively. The hydrothermal reaction was conducted at 150°C for 12h. The structure of hexagonal WO3 nanowire obtained presents complex net structure with higher specific surface area, which improves the photocatalytic activity of the material. The presence of two additives, K2C2O4 and K2SO4, proved that K+ plays an important role in guiding the growth of WO3 nanowire. The…
Tungsten oxide nanowire may be prepared by hydrothermal method using Na2WO4?2H2O and HCl as raw materials with Na2SO4 as additive. Hydrothermal Method to Prepare Tungsten Trioxide Nanowire 1. Weigh 3.68g (0.011mol) Na2WO4?2H2O into 20ml deionized water and stir it to dissolve; 2. Add 3M HCl to the above solution dropwise, stir it until the white precipitate no longer generated, and adjust the pH≈1; 3. Add in certain amount of 0.5M Na2SO4, continue to stir for 2h and transfer the solution…
Tungsten oxide nanotube requires extra coating and etching processes if it is prepared by traditional producing methods, whose quality greatly depends on the control of processing steps. Therefore, the hollow WO3 nanofibers may be directly manufactured by using the coaxial electrospinning technology to simplify the process. Principle of Coaxial Electrospinning Technology The hollow nanotube is generally obtained by coaxially electrospinning readily soluble or volatile substance and then removing the core layer by dissolving or heating. In general, mineral oil and…
99% sodium tungstate’s impurities may be determined using lanthanum hydroxide as coprecipitation agent by inductively coupled plasma atomic emission spectrometry (ICP-AES method) after coprecipitation separation and concentration of these impurities. These trace metal impurities are calcium, tin, cobalt, copper, iron, manganese, zinc, and nickel, etc. The determination of trace metal impurities must be performed on a high resolution spectrometer if the ICP-AES method is adopted directly. That is because the matrix tungsten often has severe spectral overlap interference with the…
Fe-doped tungstic acid may be prepared using sodium tungstate and iron salts as materials. Since Fe initiates the Fenton reaction, the photocatalytic activity of tungstic acid is greatly improved. Also, this is a heterogeneous reaction that avoids the loss of iron ions and thus enables the reuse of the catalyst. Tungsten compounds have a wide range of applications in the field of photocatalysis. These compounds can undergo intramolecular charge transfer under the irradiation of ultraviolet light, thereby triggering the degradation…
Industrial grade tungstic acid is an intermediate compound of ammonium paratungstate (APT) in powder metallurgy. Preparation of Industrial Grade Tungstic Acid Step 1: Add tungstic acid raw material with a purity of 99.95% into the inorganic acid solution, the mass ratio of the inorganic acid solution to the tungstic acid raw material is 1:1 to 2:1, ultrasonic irradiation oscillation for 3h-6h. The temperature is controlled at the range of 20°C~40°C, suction filtration to obtain filter cake solid; Step 2: Put…
High-purity tungstic acid is a new chemical material with a wide range of application prospects, which may be prepared by a new process of dissociation – slurrying – acid decomposition, with purity higher than 99.99% and average particle size of 0.61μm. The process is stable and easy to operate with high transformation rate. Tungstic acid may be produced by acid decomposition scheelite concentrate method, ammonium paratungstate method, artificial scheelite method, ammonium paratungstate sodium method, and the method of acid decomposition…
Nano grain size tungstic acid may be synthesized by chemical precipitation method using ammonium metatungstate (AMT) and hydrochloric acid (HCL) as raw materials, and the agglomeration of nanoparticles may be effectively improved with the addition of ethanol. And nano tungstic acid with high purity, small particle size and good dispersion may be prepared by liquid phase precipitation method in the alcohol-water system. Synthesis of Monodisperse Tungstic Acid Nanoparticles by UV Irradiation Monodisperse tungstic acid nanoparticles with an average particle size…